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Delocalized spin states at zigzag termini of armchair graphene nanoribbon

Delocalized spin states at zigzag termini of armchair graphene nanoribbon

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4. February 2025

Using scanning tunneling microscopy and spectroscopy we demonstrate a revival of magnetism in 7-armchair nanoribbon by unpassivated atoms at the termini. Namely, a pair of intense Kondo resonances emerges at the peripheries of zigzag terminus revealing the many-body screening effects of local magnetic moments. Although Kondo resonance originates from a missing local orbital, it extends to a distance of 2.5 nm along the edge of the ribbon. The results are complemented by density functional theory calculations which suggest a possible coupling between Kondo states despite screening effects of substrate electrons. These findings indicate a possibility to restore intrinsic magnetic ordering in graphene nanoribbon without major structural modifications

DOI: https://doi.org/10.1038/s41598-024-62624-9

Curvature induced layer dilation in thin smectic films

Curvature induced layer dilation in thin smectic films

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4. February 2025

Smectic A (SmA) liquid crystals can be viewed as model systems for lamellar structures. They bridge the study of broken orientational symmetry, the statistical mechanics of membranes, and the long-range periodic order in crystals. Among others, they provide an arena to systematically study the effects of nonlinear elasticity. We demonstrated that a nonlinear energy description is required which is not captured in the classical Landau-de Gennes-Ginsburg model in order to explain the observed layer spacing of highly curved SmA layers. Using X-ray diffraction, we quantitatively determined the dilation of bent layers distorted by antagonistic anchoring. We showed that combined X-ray measurements and theoretical modeling allow for the quantitative determination of the number of curved smectic layers and their thickness in dilated regions.

DOI: https://doi.org/10.1103/PhysRevLett.134.018101

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