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To visualize the intrinsic band structure of armchair graphene nanoribbon and verify theories, the terminus is covalently bonded to Au-coated tip. Tunneling spectroscopies with these suspended nanoribbons exhibit symmetric onsets of conduction and valence bands around zero bias. From these results, a value of 2.78 eV for the band gap is determined which agrees very well with theoretical calculations.

Interestingly, the formation of C—Au bond suppresses Schottky contact resistance which is one of the essential prerequisites for future nanoribbon electronics.

DOI: https://onlinelibrary.wiley.com/doi/10.1002/pssr.202470030

We developed flexible and eco-friendly composite films, prepared by vacuum filtration or solvent casting method from the native or carboxylated cellulose nanofibrils and high electrically and thermally conductive 2D titanium carbide (Ti₃C₂T_x) MXenes. The electrostatic repulsion and hydrogen bonding between the hydrophilic surface/terminal groups on cellulose and MXene was shown to render their self-assembly distribution and organization into morphologically differently structured films with, consequently, different functional properties. A strong enhancement (for an order of magnitude) of the dielectric permittivity on increasing MXene content demonstrates the potential of developed material for applications in flexible dielectric and piezoelectric devices.

DOI: https://doi.org/10.1063/5.0232250